Danho
ZIMSEC O Level · 4024/2 · N2025

Chemistry Paper 2 November 2025

Questions
75
Total marks
115
Time allowed
120 min
Syllabus code
4024/2

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Questions
75
Pass mark
45
Sit this paper

Answer every question in the printed order, get marked at the end, then see the answers.

The questions

Section A

Section A, Question 1

[2 marks]Kinetic theory and states of matter
A pure substance is heated steadily from a solid. On its heating curve, B-C is a flat plateau (melting) and D-E is a later flat plateau (boiling), with the temperature rising continuously in between, over region C-D, and rising again after E. In region C-D, the substance is
  1. Aliquid, since it lies between the melting plateau and the boiling plateau, where only one phase is warming up.
  2. Bsolid, since region C-D comes soon after the melting plateau B-C and solids come before liquids on the graph.
  3. Ca mixture of solid and liquid, since melting is still finishing off gradually through this region.
  4. Dgas, since the temperature is rising and rising temperature always means the substance has become a gas.
[1 marks]Kinetic theory and states of matter
On a heating curve of a pure substance, the boiling plateau is at D-E (liquid and gas coexisting at constant temperature), and after E the temperature rises again into region E-F. State the physical state of the substance in region E-F.

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[1 marks]Kinetic theory and states of matter
On the heating curve of a pure solid being warmed into a gas, region B-C is a flat plateau occurring straight after the solid has been warming up. Name the process occurring in region B-C.

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[1 marks]Kinetic theory and states of matter
On the heating curve of a pure liquid being warmed into a gas, region D-E is a flat plateau occurring after the liquid has been warming up and before the substance warms further as a gas. Name the process occurring in region D-E.

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[1 marks]Periodic table
A periodic table extract shows Groups I and II as two narrow columns on the left, then a gap, then a wide block of elements running between Group II and Group III, with element X inside that wide block. X's position in the table is best stated as
  1. APeriod 1, since X is the very first element drawn in the wide block reading left to right.
  2. Bthe transition metal (d) block, between Group II and Group III.
  3. CGroup I, since X is drawn to the right of the narrow columns that represent the main groups.
  4. DGroup VII, since elements drawn towards the right of a periodic table extract are always the halogens.
[1 marks]Periodic table
Element X is placed in the transition metal (d) block of the Periodic Table, between Group II and Group III. State the property of X's electrons that is used to place it in this block.

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[1 marks]Periodic table
Element X sits in the transition metal (d) block of the Periodic Table. The oxide formed by X is expected to be
  1. Aneutral, because transition metals do not react with oxygen to form oxides at all.
  2. Bacidic, because every element that is not in Group I or II forms an acidic oxide.
  3. Camphoteric, because every transition metal oxide reacts with both acids and alkalis.
  4. Dbasic, because it is an ionic metal oxide that reacts with dilute acids to form a salt and water.

Section A, Question 2

[1 marks]Kinetic theory and states of matter
In a table comparing the three states of matter by how their particles are arranged at room temperature, state how the particles are arranged in a solid.

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[1 marks]Kinetic theory and states of matter
In a table comparing the three states of matter by how their particles are arranged at room temperature, the row for a liquid should state that its particles are
  1. Aclose together but randomly arranged, free to slide past one another.
  2. Bfar apart and randomly arranged, moving rapidly in every direction.
  3. Cregularly arranged and widely spaced, sliding slowly past each other.
  4. Dtightly packed in a regular pattern, only vibrating about fixed points.
[1 marks]Kinetic theory and states of matter
In a table comparing the three states of matter by how their particles are arranged at room temperature, the row for a gas should state that its particles are
  1. Afar apart and randomly arranged, moving rapidly in every direction.
  2. Bwidely spaced in a fixed regular pattern, vibrating rapidly in place.
  3. Ctightly packed in a regular pattern, only vibrating about fixed points.
  4. Dclose together but randomly arranged, free to slide past one another.
[1 marks]Kinetic theory and states of matter
A bottle of perfume is opened and its sweet smell is sensed metres away a short time later, without any stirring of the air. Name the process by which the perfume particles spread through the air.

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[2 marks]Atomic structure
A pure substance made of only one type of atom, which cannot be broken down into anything simpler by a chemical reaction, is best described as
  1. Aan element, since it contains only one type of atom and cannot be split chemically.
  2. Ban isotope, since every pure substance made of one type of atom is automatically an isotope.
  3. Ca compound, since it always has a fixed chemical formula.
  4. Da mixture, since it is a single pure substance with no other substances added.
[2 marks]Formulae and equations
Calcium chloride is formed directly from its two elements, calcium metal and chlorine gas. Write the balanced chemical equation for this reaction, including state symbols.

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Section A, Question 3

[2 marks]Acids, bases and salts
Sulphur dioxide, an acidic non-metal oxide, reacts with the base sodium hydroxide to give a sodium salt and water: SO2(g) + NaOH(aq) -> a sodium salt + H2O(l). This reaction is classified as a
  1. Aneutralisation reaction, because an acidic oxide reacts with a base to give a salt and water.
  2. Boxidation reaction, because sulphur dioxide gains oxygen during the reaction.
  3. Cthermal decomposition, because sodium hydroxide breaks down on heating with sulphur dioxide.
  4. Ddisplacement reaction, because sodium displaces sulphur from the sulphur dioxide.
[1 marks]Acids, bases and salts
Sulphur dioxide, SO2, reacts with the base sodium hydroxide to give a salt and water, a neutralisation reaction. Give the reason SO2 is able to act as the acid in this reaction.

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[1 marks]Environmental chemistry
Sulphur dioxide is a pollutant gas that can be removed by reacting it with an alkali such as sodium hydroxide (or, industrially, calcium hydroxide slurry). This reaction is important for removing pollutants because it
  1. Aremoves carbon dioxide from the waste gases, which is the main gas responsible for acid rain.
  2. Bturns sulphur dioxide into a second harmful gas that is easier to filter out using a simple dust filter.
  3. Cconverts the acidic gas into a harmless dissolved salt instead of letting it escape and dissolve in rain water.
  4. Dcools waste gases down so that they can be released safely from a tall chimney without causing acid rain.
[1 marks]Bonding and structure
A dot and cross diagram shows an oxide of a Group II metal: one ion has completely lost two electrons to become a 2+ ion with a full outer shell, and the other has completely gained those two electrons to become a 2- ion with a full outer shell. The bonding in this oxide is
  1. Aionic, since electrons are completely transferred from one atom to the other, forming oppositely charged ions.
  2. Bmetallic, since the diagram shows two atoms joined together in a lattice structure.
  3. Cvan der Waals, since the ions shown are only weakly attracted to each other.
  4. Dcovalent, since a full outer shell of electrons is always the result of covalent bonding.
[1 marks]Formulae and equations
A dot and cross diagram shows an ionic oxide formed between a cation with 20 protons and an anion with 8 protons, each with a charge of size 2. State the chemical formula of the oxide.

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[2 marks]Bonding and structure
An ionic oxide, CaO, is formed from a Ca2+ ion and an O2- ion held together in a giant lattice by strong electrostatic forces acting in all directions. At room temperature and pressure, this compound is
  1. Aa solid, because covalent bonds between the ions require a huge amount of energy to break.
  2. Ba gas, because ionic compounds always have very low melting and boiling points.
  3. Ca liquid, because the strong forces between the ions keep them constantly sliding past one another.
  4. Da solid, because a great deal of energy is needed to overcome the many strong ionic forces, giving a high melting point.

Section A, Question 4

[1 marks]Organic chemistry
In the cracking of paraffin, mineral wool soaked in paraffin is heated and the vapours are passed over a hot solid before the gaseous product is tested with bromine water. Name the catalyst commonly used for this cracking reaction in the school laboratory.

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[1 marks]Organic chemistry
Paraffin is cracked by passing its heated vapour over a catalyst, and the gaseous product formed is bubbled through orange/brown bromine water. The observation made in the bromine water is that it
  1. Aforms a white precipitate that slowly dissolves back into solution.
  2. Bis decolourised (turns from orange/brown to colourless).
  3. Cturns from colourless to a deep blue colour.
  4. Dbubbles vigorously and gives off a colourless gas with a pungent smell.
[2 marks]Organic chemistry
Cracking paraffin produces a gas that decolourises bromine water when bubbled through it in test tube B. The reason bromine water is decolourised is that
  1. Athe cracked gas reduces the bromine to hydrogen bromide gas, which then escapes from the solution.
  2. Bthe cracked gas is an alkane, and alkanes always react rapidly with bromine water in the dark.
  3. Cthe cracked gas contains a carbon to carbon double bond, which undergoes addition with the bromine.
  4. Dthe cracked gas dissolves the bromine physically, without any chemical reaction taking place at all.
[2 marks]Organic chemistry
Ethene gas reacts with steam, in the presence of a catalyst, to form ethanol. Write the balanced chemical equation for this reaction, including state symbols.

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[1 marks]Organic chemistry
Ethene gas reacts with steam, C2H4(g) + H2O(g) -> C2H5OH(g), with the carbon to carbon double bond opening so that H and OH add directly across it and no other product is formed. This reaction is classified as
  1. Aan oxidation reaction, since ethene gains oxygen atoms from the steam.
  2. Ba condensation reaction, since a small molecule is lost as the product forms.
  3. Ca substitution reaction, since one atom in ethene is replaced by an OH group.
  4. Dan addition (hydration) reaction, since water adds directly across the double bond with nothing else produced.
[1 marks]Organic chemistry
In the manufacture of ethanol from mealie meal by fermentation, the mealie meal (which contains starch) is boiled before yeast is added. The mealie meal is boiled first because boiling
  1. Aremoves the ethanol already present in the mealie meal before new ethanol can be fermented from it.
  2. Bcools the mixture down to a temperature the yeast enzymes can survive before fermentation begins.
  3. Cconverts the starch into simpler sugars that the yeast can actually ferment, and sterilises the mixture.
  4. Devaporates all the water from the mealie meal so that only pure starch is left for the yeast to use.

Section A, Question 5

[2 marks]Rates of reaction
In the contact process for manufacturing sulphuric acid, sulphur dioxide reacts with oxygen over a vanadium(V) oxide catalyst to reach dynamic equilibrium. Write the balanced equation for this step, including the equilibrium sign.

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[1 marks]Rates of reaction
In a reversible reaction inside a closed system, a point is reached where the rate of the forward reaction equals the rate of the reverse reaction, so the amounts of reactants and products stop changing even though both reactions are still happening. This state is called
  1. Astatic equilibrium, since nothing at all is moving or reacting once this point is reached.
  2. Bcompletion, since the reaction has stopped happening in both directions.
  3. Cdynamic equilibrium, since both reactions still occur but at equal, opposing rates.
  4. Dsaturation, since no more product can dissolve once this point is reached.
[2 marks]Rates of reaction
State two of the conditions needed for the manufacture of sulphuric acid by the contact process (excluding the pressure used).

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[1 marks]Rates of reaction
The contact process for manufacturing sulphuric acid is run at a temperature of about 450 degrees C with a vanadium(V) oxide catalyst. State the third condition needed, concerning the pressure used.

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[1 marks]Environmental chemistry
Unreacted sulphur dioxide and sulphur trioxide can escape from a sulphuric acid plant into the atmosphere. The main environmental impact of this is that the gases
  1. Adissolve in rain water to form acid rain, which damages lakes, forests and buildings.
  2. Bsettle as a fine white dust that blocks sunlight from reaching plant leaves.
  3. Ctrap heat in the atmosphere directly, causing global warming on their own.
  4. Ddeplete the ozone layer, letting more ultraviolet radiation reach the ground.
[1 marks]Chemistry in society
State one industrial use of sulphuric acid.

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Section B

Section B, Question 6

[2 marks]Formulae and equations
A hydrocarbon X consists of 86% carbon by mass (so 14% hydrogen by mass). Using 100 g of X, calculate the empirical formula of X.

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[1 marks]Formulae and equations
A hydrocarbon X has empirical formula CH2 (empirical formula mass 14) and a relative molecular mass of 56. Determine the molecular formula of X.

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[2 marks]Organic chemistry
A hydrocarbon X has molecular formula C4H8. A simple chemical test to identify X as an alkene is to add X to (or shake it with) bromine water, since X will
  1. Aform a white precipitate with the bromine water, because C4H8 is insoluble in water.
  2. Bleave the bromine water unchanged, because C4H8 is a saturated hydrocarbon with no double bond.
  3. Cturn the bromine water blue-black, because C4H8 reacts with bromine the same way starch reacts with iodine.
  4. Ddecolourise the bromine water, because C4H8 has a carbon to carbon double bond that adds bromine across it.
[1 marks]Organic chemistry
Bromine water is decolourised when shaken with a hydrocarbon X of molecular formula C4H8. State the structural feature of X responsible for this reaction.

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[2 marks]Separation techniques
In the fractional distillation of a water/ethanol mixture, the column above the flask is packed with glass beads. Their function is to
  1. Areact with the ethanol vapour, converting some of it into a more volatile compound.
  2. Babsorb water vapour chemically, leaving only ethanol vapour to travel up the column.
  3. Ccool the flask directly, lowering the boiling point of the ethanol so it distils over first.
  4. Dprovide a large surface for repeated condensing and re-vaporising, enriching the rising vapour in ethanol.
[2 marks]Separation techniques
In the fractional distillation of a water/ethanol mixture, a thermometer is placed with its bulb level with the side arm leading to the condenser, at the top of the column. The thermometer is positioned there because it needs to
  1. Ameasure the temperature of the vapour about to leave and be collected, confirming it is (nearly) pure ethanol.
  2. Bprevent vapour from escaping up the column before it has had a chance to condense on the glass beads.
  3. Cmeasure the boiling point of water, since water is the substance being collected as the distillate.
  4. Dmeasure the temperature inside the flask, to know when all the liquid has finished boiling away.
[1 marks]Separation techniques
Ethanol (boiling point 78 degrees C) and water (boiling point 100 degrees C) are separated by fractional distillation. State the property of the two liquids that makes this separation possible.

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[2 marks]Rates of reaction
In the Haber process, N2(g) + 3H2(g) <=> 2NH3(g), a pressure of about 200 atmospheres is used in the converter. This pressure is chosen because it
  1. Acools the reacting gases, which is needed since the forward reaction is exothermic.
  2. Bincreases the rate of the reverse reaction only, so more nitrogen and hydrogen are regenerated.
  3. Cshifts the equilibrium towards the side with fewer gas molecules, increasing the yield of ammonia.
  4. Dstops the reaction from ever reaching equilibrium, so ammonia keeps forming indefinitely.
[2 marks]Rates of reaction
In the Haber process, N2(g) + 3H2(g) <=> 2NH3(g), delta H negative, a temperature of about 450 degrees C is used rather than a much lower temperature. This is because a lower temperature would give
  1. Athe same yield of ammonia at equilibrium, but a much faster reaction rate than at 450 degrees C.
  2. Ba higher yield of ammonia at equilibrium, but the reaction would be too slow to be worth running.
  3. Ca lower yield of ammonia at equilibrium, and the reaction would also be too slow to be worth running.
  4. Dthe same yield and the same rate, so temperature makes no real difference to the process at all.

Section B, Question 7

[2 marks]Acids, bases and salts
Calcium carbonate solution reacts completely with hydrochloric acid, giving calcium chloride, water and carbon dioxide gas. Write the balanced equation for this reaction, including state symbols.

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[2 marks]Stoichiometry
A volume of 25.00 cm3 of 0.35 mol dm-3 calcium carbonate solution is completely neutralised by hydrochloric acid. Calculate the number of moles of calcium carbonate that reacted.

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[2 marks]Stoichiometry
A volume of 25.00 cm3 of 0.35 mol dm-3 calcium carbonate solution (0.00875 mol of CaCO3) is completely neutralised by hydrochloric acid, CaCO3(aq) + 2HCl(aq) -> CaCl2(aq) + H2O(l) + CO2(g). Calculate the number of moles of hydrochloric acid that reacted.

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[2 marks]Stoichiometry
A 25.00 cm3 sample of calcium carbonate solution needed 19.50 cm3 of hydrochloric acid for complete neutralization, using 0.0175 mol of HCl. Calculate the concentration of the HCl, in mol dm-3.

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[2 marks]Rates of reaction
Ammonia is manufactured industrially by reacting two gases together over an iron catalyst, N2(g) + 3H2(g) <=> 2NH3(g). The two gases used are
  1. Acarbon dioxide and hydrogen.
  2. Bnitrogen and hydrogen.
  3. Cnitrogen and oxygen.
  4. Doxygen and hydrogen.
[1 marks]Chemistry in society
State one industrial use of ammonia.

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[2 marks]Air
Ammonia is manufactured from nitrogen and hydrogen gas by the Haber process. The sources of these two gases are
  1. Anitrogen from natural gas and hydrogen from the fractional distillation of liquid air.
  2. Bnitrogen from the electrolysis of brine and hydrogen from the fractional distillation of crude oil.
  3. Cnitrogen from the fractional distillation of liquid air and hydrogen from natural gas reacted with steam.
  4. Dnitrogen from the fractional distillation of petroleum and hydrogen from limestone heated strongly.
[2 marks]Environmental chemistry
The Haber process (manufacture of ammonia) requires a great deal of energy from burning fossil fuels, and ammonia-based fertilisers can run off into rivers and lakes. An environmental problem this causes is
  1. Adepletion of the ozone layer, since ammonia reacts directly with ozone high in the atmosphere.
  2. Beutrophication of rivers and lakes, where excess nutrients cause algae to grow explosively, then die and decompose, using up dissolved oxygen and killing aquatic life.
  3. Cglobal cooling, since burning fossil fuels for the process reflects sunlight back into space.
  4. Dpermanent soil acidification, since ammonia itself is a strong acid that lowers soil pH wherever it is used.

Section B, Question 8

[1 marks]Organic chemistry
Starch is boiled with dilute hydrochloric acid to give substance B, which is then reacted with yeast at 37 degrees C to give ethanol and a gas. Name substance B.

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[1 marks]Organic chemistry
Ethanol, formed by fermenting glucose with yeast, is later reacted with acidified potassium dichromate(VI) to give a liquid D and water. Name liquid D.

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[1 marks]Organic chemistry
Yeast ferments glucose at 37 degrees C to give ethanol and a gas, C. Name gas C.

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[2 marks]Organic chemistry
Starch is converted to glucose using dilute hydrochloric acid, and ethanol is later converted to ethanoic acid using acidified potassium dichromate(VI). The two reactions are, respectively,
  1. Aoxidation, then hydrolysis.
  2. Bfermentation, then hydrolysis.
  3. Chydrolysis, then oxidation.
  4. Dhydrolysis, then reduction.
[2 marks]Organic chemistry
Ethanol is used both in hand sanitizers and blended into petrol as a fuel. The reason it suits both uses is that ethanol
  1. Areacts violently with bacteria on the skin, generating heat that both sanitizes the skin and powers an engine.
  2. Bis completely unreactive, so it neither kills bacteria nor releases energy when burnt, making it safe for both uses.
  3. Ckills microorganisms at a suitable concentration and evaporates quickly (suiting a sanitizer), and burns cleanly while mixing completely with petrol (suiting a fuel blend).
  4. Donly dissolves in water and not in petrol, so it cannot actually be blended into petrol as a fuel at all.
[2 marks]Organic chemistry
Crude oil contains hydrocarbons of many different chain lengths and boiling points. To obtain separate hydrocarbon fractions from it, crude oil is
  1. Aheated until it vaporises and passed into a fractionating column, where each fraction condenses and is drawn off at the height matching its own boiling point range.
  2. Breacted with steam, which converts the mixture directly into pure petrol and pure diesel.
  3. Ccooled slowly until each hydrocarbon freezes out in turn, from the highest boiling point to the lowest.
  4. Dcracked over a hot catalyst, which converts every hydrocarbon present into a single pure fraction.
[2 marks]Water
In a septic tank, raw sewage enters a chamber where a scum layer forms at the top and sludge settles at the bottom, before a liquid effluent leaves for further treatment. Inside the tank, this happens because
  1. Aaerobic bacteria use dissolved oxygen in the sewage to burn off the organic solids completely, leaving only clean water.
  2. Banaerobic bacteria digest the organic solid waste; undigested solids and dead bacteria settle as sludge, while fats and light solids float up as scum, leaving a partially clarified effluent.
  3. Cthe sewage is simply filtered through a fine mesh, which physically separates scum, sludge and effluent with no bacteria involved.
  4. Dultraviolet light from the inspection holes sterilises the sewage, killing the bacteria that would otherwise cause the scum and sludge to form.
[2 marks]Water
Effluent leaving a septic tank flows into a soak away filled with rocks before rejoining the water table. The role of the soak away is to
  1. Achemically neutralise any acids in the effluent using the alkaline rock surface before it reaches the soil.
  2. Bcool the hot effluent down to the temperature of the surrounding soil before it soaks away.
  3. Cevaporate the effluent completely, so that no liquid actually reaches the soil or water table at all.
  4. Dlet the effluent filter slowly through the rocks and soil, where remaining solids are filtered out and soil bacteria further break down organic matter and pathogens.
[2 marks]Water
A septic tank is built to be at least 3 m deep. This depth is needed because it
  1. Aallows sunlight to reach the bottom of the tank, which is needed to kill the anaerobic bacteria once digestion is complete.
  2. Bgives the sewage a long enough retention time for anaerobic digestion and for solids/scum to settle and rise, before clarified effluent reaches the outlet.
  3. Ckeeps the tank cool enough that anaerobic bacteria can survive, since they die at the temperatures found in a shallow tank.
  4. Dreduces the total volume of sewage the tank can hold, forcing it to be emptied and cleaned out more often.

Section B, Question 9

[2 marks]Water
Large scale water purification follows the stages: filtration, flocculation, sedimentation, then disinfection. Aluminium sulphate and chlorine are each added at one of these stages. They are added, respectively, at the
  1. Afiltration stage and the sedimentation stage.
  2. Bflocculation stage and the disinfection stage.
  3. Csedimentation stage and the flocculation stage.
  4. Ddisinfection stage and the filtration stage.
[2 marks]Water
In large scale water purification, aluminium sulphate is added at the flocculation stage and chlorine at the disinfection stage. Their roles are, respectively, to
  1. Akill harmful bacteria in the water, and neutralise charges on suspended clay particles so they clump together.
  2. Blower the pH of the water, and raise the pH of the water back to neutral before it is distributed.
  3. Cneutralise charges on fine suspended particles so they clump into larger flocs that settle out, and kill harmful bacteria/pathogens so the water is safe to drink.
  4. Dremove dissolved salts from the water, and add a pleasant taste and smell to the finished water.
[1 marks]Water
Chlorine is added to water during purification to kill harmful bacteria. If too much chlorine is added, the effect on the water is that it
  1. Abecomes completely safe with no possible drawback, since chlorine cannot ever be harmful in water.
  2. Bdevelops an unpleasant taste and smell, and may form harmful chlorinated by-products with organic matter.
  3. Closes its disinfecting power entirely, since excess chlorine reacts with itself and cancels out.
  4. Dturns cloudy and undrinkable purely from the colour of the chlorine gas itself.
[2 marks]Stoichiometry
Ammonium nitrate, NH4NO3 (relative formula mass 80), is formed from ammonia and nitric acid, NH3(g) + HNO3(aq) -> NH4NO3(s). Calculate the number of kilomoles of ammonium nitrate in 50 kg of it.

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[1 marks]Stoichiometry
Producing 50 kg of ammonium nitrate (0.625 kmol) needs 0.625 kmol of nitric acid, HNO3 (relative formula mass 63), since the equation NH3(g) + HNO3(aq) -> NH4NO3(s) is one to one. Calculate the mass of nitric acid needed, in kg.

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[2 marks]Chemistry in society
Ammonium nitrate fertiliser is an oxidising agent that is hygroscopic and can decompose explosively if heated, contaminated or stored in a large mass. Because of this, it should be stored
  1. Aanywhere convenient, since ammonium nitrate is completely inert and cannot pose a storage danger.
  2. Bin a cool, dry, well ventilated place, away from flammable materials and other reactive chemicals.
  3. Cin a sealed container with a naked flame nearby, to burn off any moisture that collects on it.
  4. Dpacked tightly together in the largest single mass possible, to save the most storage space.
[2 marks]Environmental chemistry
Plastic waste is largely non-biodegradable, and burning it releases toxic gases. A problem this causes is that
  1. Aplastics that persist for hundreds of years in landfills and oceans harm wildlife that ingest them or become entangled in them.
  2. Bplastics spontaneously catch fire in landfills, which is actually a safe and controlled way to dispose of them.
  3. Cplastics dissolve completely in seawater within a few weeks, releasing all their carbon at once as carbon dioxide.
  4. Dplastics react with rainwater to form acid rain in the same way that sulphur dioxide does.
[2 marks]Environmental chemistry
Plastic waste harms wildlife because it is non-biodegradable, and burning it releases toxic gases. These problems can best be minimised by
  1. Aswitching entirely to glass and metal packaging, since these materials never require any energy at all to produce.
  2. Bburning all plastic waste in the open as soon as it is collected, so that it never reaches landfills or oceans.
  3. Ccollecting all plastic waste and burying it as deep as possible, with no other change to how much plastic is produced.
  4. Dreducing and reusing plastic where possible, recycling what is left, and disposing of the rest in controlled landfill sites rather than open burning or dumping.
[1 marks]Environmental chemistry
State one specific action, other than reducing how much plastic is used, that helps minimise the problems caused by plastic waste disposal.

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Section B, Question 10

[1 marks]Organic chemistry
Compound B is drawn as HO-[block]-OH, an OH group on each end of a carbon block. Name the homologous series to which B belongs.

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[2 marks]Organic chemistry
Compound A is a dicarboxylic acid, HOOC-[block]-COOH, and compound B is a diol, HO-[block]-OH. When A and B chemically combine, with a small molecule eliminated at each new link formed, the type of polymerisation taking place is
  1. Aaddition polymerisation, because the two monomers add across each other's functional groups with nothing lost.
  2. Bcondensation polymerisation, because a small molecule is eliminated each time a new link forms.
  3. Chydrolysis polymerisation, because water is added to break each monomer down before it joins the chain.
  4. Dvulcanisation, because sulphur atoms are used to cross link A and B together.
[1 marks]Organic chemistry
A dicarboxylic acid A, HOOC-[block]-COOH, and a diol B, HO-[block]-OH, undergo condensation polymerisation, with water eliminated at each new link. Name the linkage formed between A and B.

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[1 marks]Organic chemistry
A dicarboxylic acid and a diol undergo condensation polymerisation, joined by ester linkages, to form a polyester. A common use of this type of polymer is
  1. Aas an anti-corrosion coating sprayed directly onto iron and steel structures.
  2. Bas a cutting tool material, since the polymer is harder than tool steel.
  3. Cas an electrical conductor in household wiring.
  4. Das fibres for making clothing, since the polymer is strong and resists creasing.
[2 marks]Rates of reaction
Hydrogen peroxide decomposes, 2H2O2(g) -> 2H2O(l) + O2(g), reaching a final volume of 100 cm3 of oxygen in about 60 s without a catalyst, but in only about 40 s when manganese(II) oxide, MnO, is present. Graphs of volume of oxygen against time for the two experiments would show that
  1. Aboth curves rise from the origin and level off at 100 cm3, with the MnO curve rising more steeply and levelling off sooner.
  2. Bboth curves rise from the origin and level off at different final volumes, since MnO changes how much oxygen is produced.
  3. Cthe MnO curve is a straight line through the origin that never levels off, while the other curve levels off at 100 cm3.
  4. Dthe curve without MnO rises more steeply at first, since no catalyst means the reaction starts out faster.
[2 marks]Rates of reaction
Hydrogen peroxide decomposes faster, and reaches its final volume of oxygen sooner, when manganese(II) oxide, MnO, is present than when it is absent. MnO speeds up the reaction because it
  1. Araises the temperature of the reaction mixture, giving the particles more kinetic energy.
  2. Bremoves some of the hydrogen peroxide from the mixture before it has a chance to decompose.
  3. Cincreases the concentration of hydrogen peroxide present at the start of the reaction.
  4. Dprovides an alternative reaction pathway with a lower activation energy, so more particles react successfully on collision.
[1 marks]Rates of reaction
Hydrogen peroxide decomposes to give the same final volume of oxygen, 100 cm3, whether or not the catalyst manganese(II) oxide, MnO, is present, although the reaction is faster with MnO. The final volume of oxygen is the same in both experiments because
  1. AMnO reacts with some of the hydrogen peroxide, using it up during decomposition.
  2. Bwithout a catalyst, less hydrogen peroxide decomposes, so less oxygen gas is released.
  3. Ca catalyst increases the amount of product formed without changing the reaction rate.
  4. Da catalyst speeds up a reaction but does not change the amount of product it can form.
[2 marks]Rates of reaction
Hydrogen and iodine react reversibly, H2(g) + I2(g) <=> 2HI(g). The effect of decreasing the pressure on the position of this equilibrium is that it
  1. Astops the reaction reaching equilibrium at all, since gas reactions require a fixed pressure to proceed.
  2. Bhas no effect on the position of equilibrium, since there are two gas molecules on each side of the equation.
  3. Cshifts to the left, decreasing the yield of HI, since lower pressure always favours the reactants.
  4. Dshifts to the right, increasing the yield of HI, since lower pressure always favours the side with more gas molecules.
[2 marks]Rates of reaction
Hydrogen and iodine react reversibly, H2(g) + I2(g) <=> 2HI(g), delta H positive (the forward reaction is endothermic). The effect of increasing the temperature on this equilibrium is that it
  1. Ahas no effect on the yield of HI, since delta H positive means temperature cannot shift the equilibrium.
  2. Bshifts to the left, decreasing the yield of HI, since raising temperature always favours the reactants regardless of delta H.
  3. Cshifts to the right, increasing the yield of HI, since raising temperature favours the endothermic (forward) direction.
  4. Dstops the reverse reaction completely, converting all the H2 and I2 present into HI.

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