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ZIMSEC O Level · 4024/2 · N2019

Chemistry Paper 2 November 2019

Questions
30
Total marks
115
Time allowed
120 min
Syllabus code
4024/2

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Questions
30
Pass mark
18
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Answer every question in the printed order, get marked at the end, then see the answers.

The questions

Question 101

[1 marks]Titration apparatus, indicators and obtaining pure crystals
A burette containing sodium hydroxide solution, NaOH(aq), is clamped above a conical flask containing dilute sulfuric acid, H2SO4(aq), with 2-3 drops of a solution Y added to the acid before the NaOH is run in from the burette. Name the analytical technique being carried out.

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Question 102

[1 marks]Titration apparatus, indicators and obtaining pure crystals
In a titration where sodium hydroxide solution, NaOH(aq), is added from a burette into a conical flask containing dilute sulfuric acid, H2SO4(aq), with 2-3 drops of a solution Y added to the acid beforehand, what is the role of solution Y?
  1. AIt is the limiting reagent that determines the maximum yield of salt formed.
  2. BIt is an indicator that changes colour to show the end point of the reaction.
  3. CIt is a catalyst that increases the rate of the neutralisation reaction.
  4. DIt is a buffer that keeps the pH of the mixture constant throughout the titration.

Question 103

[1 marks]Titration apparatus, indicators and obtaining pure crystals
After sodium hydroxide solution has completely neutralised dilute sulfuric acid to form a solution of a soluble salt, state the general method used to obtain pure, dry crystals of the salt from the resulting solution.

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Question 201

[1 marks]Atom/isotope definitions, subatomic particle counting, dot-and-cross diagram of magnesium nitride
Which of the following is the correct definition of the term 'atom'?
  1. AAn atom or group of atoms that has lost or gained one or more electrons.
  2. BAn atom with the same number of protons as another atom of the same element, but a different number of neutrons.
  3. CA group of two or more atoms chemically bonded together.
  4. DThe smallest part of an element that can take part in a chemical reaction.

Question 202

[1 marks]Atom/isotope definitions, subatomic particle counting, dot-and-cross diagram of magnesium nitride
Which of the following is the correct definition of the term 'isotope'?
  1. AAn atom with the same number of protons as another atom of the same element, but a different number of neutrons.
  2. BA group of two or more atoms of different elements chemically bonded together.
  3. CAn atom that has gained or lost electrons to acquire an overall electric charge.
  4. DAn atom with the same number of neutrons as another atom of the same element, but a different number of protons.

Question 203

[1 marks]Atom/isotope definitions, subatomic particle counting, dot-and-cross diagram of magnesium nitride
An Mg2+ ion is formed from a magnesium atom that has 12 protons and, when neutral, 12 electrons. How many electrons does the Mg2+ ion contain?
  1. A8
  2. B10
  3. C12
  4. D14

Question 301

[1 marks]Reaction type identification, limiting reagent reasoning, thermal decomposition of copper(II) nitrate
In the reaction NaOH(aq) + HCl(aq) -> NaCl(aq) + H2O(l), what type of reaction is taking place?
  1. ADisplacement.
  2. BPrecipitation.
  3. CRedox, involving the transfer of electrons between reactants.
  4. DNeutralisation.

Question 302

[1 marks]Reaction type identification, limiting reagent reasoning, thermal decomposition of copper(II) nitrate
Solid copper(II) nitrate decomposes on heating according to the equation 2Cu(NO3)2(s) -> 2CuO(s) + yNO2(g) + O2(g). What is the value of the coefficient y needed to balance this equation?
  1. A2
  2. B3
  3. C4
  4. D5

Question 303

[1 marks]Reaction type identification, limiting reagent reasoning, thermal decomposition of copper(II) nitrate
In the reaction NaOH(aq) + HCl(aq) -> NaCl(aq) + H2O(l), 0.05 mol of NaOH(aq) and 0.05 mol of HCl(aq) are initially present. If the volume of HCl(aq) added is doubled without changing its concentration (so 0.10 mol of HCl is now present, while the amount of NaOH stays at 0.05 mol), what effect does this have on the amount of NaCl formed?
  1. ANo effect -- the amount of NaCl formed stays the same, since NaOH is the limiting reagent and its amount is unchanged.
  2. BThe reaction reverses, converting the NaCl formed back into NaOH and HCl.
  3. CThe amount of NaCl formed doubles, since more HCl reacts to form more salt.
  4. DThe amount of NaCl formed halves, since the excess HCl dilutes the salt formed.

Question 401

[1 marks]Human activities and CO2, environmental effects, mitigation, other gaseous pollutants
State one human activity that contributes to the release of carbon dioxide, CO2, into the atmosphere.

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Question 402

[1 marks]Human activities and CO2, environmental effects, mitigation, other gaseous pollutants
Besides carbon dioxide, name one other gaseous pollutant that is emitted into the atmosphere.

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Question 403

[1 marks]Human activities and CO2, environmental effects, mitigation, other gaseous pollutants
Which of the following is an environmental effect of high concentrations of carbon dioxide, CO2, in the atmosphere?
  1. AGlobal warming due to the enhanced greenhouse effect.
  2. BDepletion of the ozone layer.
  3. CAcid rain formation.
  4. DEutrophication of water bodies, caused by excess nitrate and phosphate fertiliser runoff.

Question 501

[1 marks]Diffusion of ammonia and hydrogen chloride, conditions affecting diffusion, eutrophication
Cotton wool soaked in concentrated hydrochloric acid, HCl, is placed at one end of a sealed glass tube, and cotton wool soaked in concentrated ammonia solution, NH3, is placed at the other end. A white ring/powder forms inside the tube where the two gases meet and react. Where does this white ring first form, and why?
  1. AExactly in the middle of the tube, because both gases diffuse at the same rate.
  2. BAt the NH3 end only, because HCl gas does not diffuse.
  3. CCloser to the HCl end, because ammonia gas diffuses faster than hydrogen chloride gas.
  4. DCloser to the NH3 end, because hydrogen chloride gas diffuses faster than ammonia gas.

Question 502

[1 marks]Diffusion of ammonia and hydrogen chloride, conditions affecting diffusion, eutrophication
Write the balanced chemical equation, with state symbols, for the reaction between ammonia gas, NH3(g), and hydrogen chloride gas, HCl(g), that produces solid ammonium chloride.

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Question 503

[1 marks]Diffusion of ammonia and hydrogen chloride, conditions affecting diffusion, eutrophication
Cotton wool soaked in concentrated hydrochloric acid is placed at one end of a sealed glass tube, and cotton wool soaked in concentrated ammonia solution is placed at the other end, so that a white ring of ammonium chloride forms where the gases meet. Which of the following would NOT affect the time taken for this white ring to form?
  1. AThe concentration of the ammonia and hydrochloric acid used.
  2. BThe length of the glass tube used.
  3. CThe temperature of the surroundings.
  4. DThe material used to make the stopper, provided it seals the tube completely.

Question 601

[1 marks]Nitric acid production, oxidation states of sulphur, bonding in ammonium nitrate
Sulfuric acid, H2SO4, contains hydrogen (oxidation state +1) and oxygen (oxidation state -2). What is the oxidation state of sulphur in H2SO4?
  1. A-6
  2. B+4
  3. C+6
  4. D+8

Question 602

[1 marks]Nitric acid production, oxidation states of sulphur, bonding in ammonium nitrate
Hydrogen sulphide, H2S, contains hydrogen with oxidation state +1. What is the oxidation state of sulphur in H2S?
  1. A-2
  2. B-1
  3. C+1
  4. D+2

Question 603

[1 marks]Nitric acid production, oxidation states of sulphur, bonding in ammonium nitrate
Ammonium nitrate, NH4NO3, is a solid formed from oppositely charged ammonium and nitrate ions held together in a lattice; within the ammonium ion, three N-H bonds form in the usual way but the fourth forms when a lone pair on nitrogen bonds to an extra hydrogen ion. Which three types of bonding does ammonium nitrate contain overall?
  1. ACovalent, dative, and hydrogen bonding, as found in water and ammonia molecules.
  2. BIonic, metallic, and dative bonding.
  3. CIonic, covalent, and dative (coordinate) bonding.
  4. DIonic, covalent, and metallic bonding.

Question 701

[1 marks]Reactions of barium, magnesium and steam, calcium carbonate mass calculation, uses of calcium oxide
Barium metal is heated gently in air to form compound L. Compound L then reacts with water to form an aqueous solution of compound M. What is compound M?
  1. ABaCO3 (barium carbonate, formed later from M and carbon dioxide)
  2. BBaO (barium oxide, compound L, not yet reacted with water)
  3. CBa(OH)2
  4. DBaSO4 (barium sulfate, formed later from M and sulfuric acid)

Question 702

[1 marks]Reactions of barium, magnesium and steam, calcium carbonate mass calculation, uses of calcium oxide
A mass of 1.32 g of CO2(g) was collected when a sample of calcium carbonate, CaCO3, was completely decomposed by heating: CaCO3(s) -> CaO(s) + CO2(g). Using Mr(CO2) = 44 and Mr(CaCO3) = 100, calculate the mass of calcium carbonate that was heated.
  1. A1.68 g
  2. B0.03 g
  3. C3 g
  4. D6 g

Question 703

[1 marks]Reactions of barium, magnesium and steam, calcium carbonate mass calculation, uses of calcium oxide
Write a balanced chemical equation, with state symbols, for the reaction of magnesium with steam.

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Question 801

[1 marks]Hydrocarbon empirical/molecular formula, copper alloys, importance of iron
A hydrocarbon X consists of 86% carbon and 14% hydrogen by mass. The relative molecular mass of X is 56. What is the molecular formula of X?
  1. AC4H8
  2. BC2H4
  3. CC3H8
  4. DC4H10

Question 802

[1 marks]Hydrocarbon empirical/molecular formula, copper alloys, importance of iron
A hydrocarbon consists of 86% carbon and 14% hydrogen by mass, with relative molecular mass 56, giving molecular formula C4H8. To which homologous series does this hydrocarbon belong?

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Question 803

[1 marks]Hydrocarbon empirical/molecular formula, copper alloys, importance of iron
Which chemical test would show the presence of a carbon-carbon double bond (C=C) in a hydrocarbon such as C4H8?
  1. AInsert a glowing splint into the gas -- the splint relights.
  2. BAdd aqueous bromine (bromine water) -- the orange/brown colour is decolourised.
  3. CAdd aqueous sodium hydroxide -- a coloured precipitate forms.
  4. DBubble the gas through limewater -- the limewater turns milky.

Question 901

[1 marks]Hydrocarbons, isomers, combustion, substitution, alcohol/alkene/ethanoic acid interconversions, polymers
Write a balanced chemical equation for the complete combustion of propane, C3H8.

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Question 902

[1 marks]Hydrocarbons, isomers, combustion, substitution, alcohol/alkene/ethanoic acid interconversions, polymers
Methane, CH4, reacts with chlorine gas, Cl2, in the presence of ultraviolet light to form chloromethane, CH3Cl, and hydrogen chloride, HCl. What type of reaction is this?
  1. AAddition reaction.
  2. BFree radical substitution.
  3. CEsterification, the reaction between an acid and an alcohol.
  4. DNeutralisation.

Question 903

[1 marks]Hydrocarbons, isomers, combustion, substitution, alcohol/alkene/ethanoic acid interconversions, polymers
Ethanol, CH3CH2OH, can be converted directly into ethanoic acid, CH3COOH. What type of chemical reagent is needed for this conversion?
  1. AA neutralising agent, such as dilute sodium hydroxide.
  2. BA dehydrating agent, such as concentrated sulfuric acid.
  3. CA reducing agent, such as hydrogen gas with a nickel catalyst.
  4. DAn oxidising agent, such as acidified potassium dichromate(VI).

Question 1001

[1 marks]Waste disposal, pollutant sources and effects, soil pH
State a suitable method of disposing of metallic waste.

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Question 1002

[1 marks]Waste disposal, pollutant sources and effects, soil pH
Carbon monoxide, CO, is a poisonous gas released into the atmosphere. What is its main source?
  1. ABacterial decomposition of organic matter in the absence of oxygen.
  2. BIncomplete combustion of fuels.
  3. CComplete combustion of fuels.
  4. DCombustion in car engines at high temperature and pressure, forming gas from atmospheric nitrogen and oxygen.

Question 1003

[1 marks]Waste disposal, pollutant sources and effects, soil pH
Write a balanced ionic equation to show how calcium oxide, CaO, neutralises excess acid, H+, in acidic soil.

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