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ZIMSEC O Level · 5071/2 · N2013

Chemistry Paper 2 November 2013

Questions
24
Total marks
85
Time allowed
120 min
Syllabus code
5071/2

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Questions
24
Pass mark
15
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Answer every question in the printed order, get marked at the end, then see the answers.

The questions

Question 101

[1 marks]Atomic structure, ions and covalent bonding
Fig. 1 shows structures of four atoms/ions, A, B, C and D, drawn as nucleus-and-shell diagrams. Structures A and D have the same number of protons but different numbers of neutrons. Which two structures together represent a pair of isotopes?
  1. AA and D
  2. BA and B
  3. CB and C
  4. DC and D

Question 102

[1 marks]Atomic structure, ions and covalent bonding
In Fig. 1, atom A forms a covalent compound with hydrogen, shown by a dot-and-cross diagram in which A shares one electron pair with each of four hydrogen atoms. What is the name of this compound?

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Question 103

[1 marks]Atomic structure, ions and covalent bonding
Methane (CH4) is the covalent compound formed when atom A in Fig. 1 bonds with four hydrogen atoms. Which of the following statements about methane is correct?
  1. AIt has a low boiling point because its molecules are held together by weak intermolecular forces.
  2. BIt is highly soluble in water.
  3. CIt exists as a giant ionic lattice at room temperature.
  4. DIt is a good conductor of electricity in the solid state.

Question 201

[1 marks]Oxides, the pH scale and industrial gases
Which of the following Period 3 oxides is amphoteric, reacting with both acids and bases?
  1. ASodium oxide, Na2O, a basic oxide that reacts only with acids
  2. BAluminium oxide, Al2O3
  3. CMagnesium oxide, MgO, a basic oxide that reacts only with acids
  4. DSilicon dioxide, SiO2, an acidic oxide that reacts only with bases

Question 202

[1 marks]Oxides, the pH scale and industrial gases
Which of the following pH ranges best describes lemon juice?
  1. ApH 1-2
  2. BpH 7
  3. CpH 10-12
  4. DpH 3-6

Question 203

[1 marks]Oxides, the pH scale and industrial gases
Which gas is manufactured by the electrolysis of water, is used in the manufacture of ammonia, and is identified because it burns with a 'pop' sound when a lit splint is applied to it?

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Question 301

[1 marks]Reactions of copper and its compounds, moles and ionic equations
In an experiment, 2.4 g of magnesium (Mr = 24) reacts completely with a sample of black solid copper(II) oxide (Mr = 80), according to Mg + CuO -> MgO + Cu. What mass of copper(II) oxide reacted?
  1. A16 g
  2. B4.0 g
  3. C8 g
  4. D6.4 g

Question 302

[1 marks]Reactions of copper and its compounds, moles and ionic equations
Copper metal is heated strongly in oxygen to form a black solid, B. What is B?
  1. ACopper hydroxide
  2. BCopper(I) oxide
  3. CCopper(II) oxide
  4. DCopper carbonate

Question 303

[1 marks]Reactions of copper and its compounds, moles and ionic equations
Write the ionic equation, including state symbols, for the reaction between barium ions and sulfate ions to form the white precipitate barium sulfate.

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Question 401

[1 marks]Electrolysis and electroplating
Molten lead(II) bromide is electrolysed using inert graphite electrodes. Which equation represents the reaction that occurs at the cathode?
  1. A2H2O -> O2 + 4H+ + 4e-
  2. B2Br- -> Br2 + 2e-
  3. CPb -> Pb2+ + 2e-
  4. DPb2+ + 2e- -> Pb

Question 402

[1 marks]Electrolysis and electroplating
Aqueous copper(II) sulfate is electrolysed using copper electrodes. What happens at the anode?
  1. ACu2+ ions are reduced to copper atoms (Cu2+ + 2e- -> Cu).
  2. BWater molecules are oxidised to oxygen gas.
  3. CHydroxide ions are reduced to hydrogen gas.
  4. DCopper atoms are oxidised to Cu2+ ions (Cu -> Cu2+ + 2e-).

Question 403

[1 marks]Electrolysis and electroplating
What observation is made at the anode during the electrolysis of molten lead(II) bromide using graphite electrodes?
  1. ABubbles of a colourless gas with a pop sound are produced.
  2. BThe electrolyte turns blue.
  3. CA white precipitate forms in the melt.
  4. DA red-brown vapour is produced.

Question 501

[1 marks]The halogens
Which statement correctly compares the physical states of bromine and iodine at room temperature?
  1. ABromine is a liquid and iodine is a solid.
  2. BBoth bromine and iodine are gases.
  3. CBoth bromine and iodine are solids.
  4. DBromine is a solid and iodine is a liquid.

Question 502

[1 marks]The halogens
Which of the following is a chemical property shared by both bromine and iodine?
  1. ABoth readily lose electrons to form positive ions.
  2. BBoth are strong reducing agents.
  3. CBoth have seven electrons in their outer electron shell.
  4. DBoth form basic oxides.

Question 503

[1 marks]The halogens
When chlorine gas is bubbled through aqueous potassium bromide, 2KBr(aq) + Cl2(g) -> 2KCl(aq) + Br2(g), what type of reaction is this (name the general reaction type)?

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Question 601

[1 marks]The Contact process and ammonium sulphate
Fig. 5's flow diagram has the sequence: box A (where sulfur is burned in dry air) -> box B -> box C (fed with additional oxygen) -> box D (fed with water, producing concentrated sulfuric acid) -> box E (releasing waste gases). Which labelled box is the catalytic converter, where sulfur dioxide is converted to sulfur trioxide?
  1. AC
  2. BA
  3. CB
  4. DE

Question 602

[1 marks]The Contact process and ammonium sulphate
In the Contact process, sulfur dioxide reacts with oxygen (2SO2(g) + O2(g) <=> 2SO3(g)) in the presence of a catalyst. Which substance is used as this catalyst?
  1. AIron, the catalyst used in the Haber process for ammonia
  2. BPlatinum, used as a catalyst in catalytic converters for cars
  3. CVanadium(V) oxide
  4. DAluminium oxide, an amphoteric oxide sometimes used as a catalyst support

Question 603

[1 marks]The Contact process and ammonium sulphate
Ammonium sulfate fertiliser is manufactured by reacting sulfuric acid with a base, then evaporating and crystallising the solution. Which base is reacted with the sulfuric acid?

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Question 701

[1 marks]Cracking, alkenes and homologous series
Paraffin of formula C12H26 is passed as a vapour over a hot catalyst, breaking it down into ethene (C2H4) and a smaller alkane. What is the name of this process?
  1. AFractional distillation
  2. BCracking
  3. CPolymerisation
  4. DFermentation

Question 702

[1 marks]Cracking, alkenes and homologous series
When paraffin C12H26 is cracked over a hot catalyst, it forms ethene (C2H4) and a liquid alkane A, according to C12H26 -> A + C2H4. What is the molecular formula of A?

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Question 703

[1 marks]Cracking, alkenes and homologous series
What is observed when ethene gas is bubbled through orange bromine water?
  1. AThe limewater turns milky, as it does when testing for carbon dioxide gas.
  2. BThe bromine water is decolourised.
  3. CA pop sound is heard, as when testing for hydrogen gas with a lit splint.
  4. DA white precipitate forms, as seen when testing for halide ions with silver nitrate.

Question 801

[1 marks]Ethanol: dehydration, combustion and energetics
Ethanol vapour is passed over a heated aluminium oxide (Al2O3) catalyst, producing a gas Y and water. What is gas Y?

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Question 802

[1 marks]Ethanol: dehydration, combustion and energetics
The complete combustion of 46 g of ethanol releases 1380 kJ of energy. How much energy is released when 0.5 moles (23 g) of ethanol are completely burnt?
  1. A345 kJ
  2. B690 kJ
  3. C1380 kJ
  4. D2760 kJ

Question 803

[1 marks]Ethanol: dehydration, combustion and energetics
In an experiment, ethanol is heated using an electric heater rather than a naked (Bunsen) flame to produce gas Y. Why is an electric heater used?
  1. AEthanol is highly flammable, so heating it with a naked flame would be a fire hazard.
  2. BEthanol does not conduct heat well, so a flame would be ineffective.
  3. CA naked flame cannot reach a high enough temperature to heat ethanol.
  4. DEthanol reacts chemically with the products of a naked flame.

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