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ZIMSEC O Level · 5071/2 · N2014

Chemistry Paper 2 November 2014

Questions
27
Total marks
85
Time allowed
120 min
Syllabus code
5071/2

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Questions
27
Pass mark
17
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Answer every question in the printed order, get marked at the end, then see the answers.

The questions

Question 101

[1 marks]Subatomic particles, ions and bonding
Chlorine-35, ³⁵Cl, has atomic (proton) number 17. State the number of neutrons in one atom of chlorine-35.

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Question 102

[1 marks]Subatomic particles, ions and bonding
Which statement correctly describes a difference between a chlorine atom, Cl, and a chloride ion, Cl⁻?
  1. AThe chloride ion has one more electron than the chlorine atom, giving it a negative charge.
  2. BThe chloride ion has one fewer electron than the chlorine atom, giving it a positive charge.
  3. CThe chloride ion has one more proton than the chlorine atom.
  4. DThe chloride ion has one more neutron than the chlorine atom.

Question 103

[1 marks]Subatomic particles, ions and bonding
Carbon tetrachloride, CCl4, is a liquid at room temperature while calcium chloride, CaCl2, is a solid. This is because...
  1. ACCl4 molecules are held together by weak intermolecular forces of attraction, while Ca²⁺ and Cl⁻ ions in CaCl2 are held together by strong electrostatic forces.
  2. BCCl4 is made up of ions while CaCl2 is made up of covalent molecules.
  3. CCCl4 has a higher boiling point than CaCl2 because its molecules are larger.
  4. DCCl4 molecules are held together by strong intermolecular forces of attraction, while ions in CaCl2 are held together by weak electrostatic forces.

Question 201

[1 marks]Types of reaction, oxidation number and the mole
Chlorine gas is bubbled through sodium bromide solution: Cl2 + 2NaBr → Br2 + 2NaCl. What type of reaction is this?
  1. Aprecipitation
  2. Bredox
  3. Chydrolysis
  4. Dneutralisation

Question 202

[1 marks]Types of reaction, oxidation number and the mole
Potassium chlorate (V), KClO3, breaks down on strong heating to potassium chloride and oxygen only, according to the equation 2KClO3 → 2KCl + 3O2. What volume of oxygen, measured at r.t.p (molar gas volume = 24 dm3/mol), can be produced by the complete breakdown of 10 g of KClO3? (Relative formula mass of KClO3 = 122,5)
  1. A1,92 dm3
  2. B2,69 dm3
  3. C5,76 dm3
  4. D2,88 dm3

Question 203

[1 marks]Types of reaction, oxidation number and the mole
In the name potassium chlorate (V), KClO3, what does the Roman numeral (V) represent?

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Question 301

[1 marks]Rate of reaction
Iron filings react with dilute sulfuric acid, H2SO4, to produce iron(II) sulfate and a gas. Write a balanced equation for this reaction.

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Question 302

[1 marks]Rate of reaction
In the reaction Fe + H2SO4 → FeSO4 + gas, iron filings react with dilute sulfuric acid. Name the gas produced.

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Question 303

[1 marks]Rate of reaction
In an experiment, iron filings were reacted with dilute sulfuric acid and the volume of gas produced was recorded: 0,00 cm3 at 0 min, 12,00 cm3 at 30 min, and 24,67 cm3 at 60 min. What is the rate of reaction over the first 60 minutes?
  1. A24,67 cm3/min
  2. B0,411 cm3/min
  3. C0,274 cm3/min
  4. D0,400 cm3/min

Question 401

[1 marks]Alkanes, homologous series and isomerism
Which of the following is the correct definition of the term 'isomer'?
  1. AAtoms of the same element with the same number of protons but different numbers of neutrons.
  2. BMolecules with the same molecular formula but different structural formulae.
  3. CDifferent structural forms of the same element in the same physical state.
  4. DCompounds with the same general formula and similar chemical properties, differing by CH2 between successive members.

Question 402

[1 marks]Alkanes, homologous series and isomerism
Give one reaction, other than combustion, that alkanes undergo.

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Question 403

[1 marks]Alkanes, homologous series and isomerism
Butane, C4H10, has an unbranched straight-chain isomer, butane, and one branched-chain isomer. Name the branched-chain isomer of C4H10.

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Question 501

[1 marks]Organic reactions: addition, neutralisation, esterification, oxidation, condensation and cracking
Ethene, CH2=CH2, reacts with chlorine gas, Cl2, in an addition reaction. Give the name or formula of the organic product formed.

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Question 502

[1 marks]Organic reactions: addition, neutralisation, esterification, oxidation, condensation and cracking
Propan-1-ol, CH3CH2CH2OH, is oxidised to propanoic acid, CH3CH2COOH, by heating it with an acidified oxidising agent. Name this oxidising agent.

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Question 503

[1 marks]Organic reactions: addition, neutralisation, esterification, oxidation, condensation and cracking
An alkane is cracked over an Al2O3 catalyst at 500°C to produce octane, C8H18, and ethene, CH2=CH2. Give the name or molecular formula of the alkane that was cracked.

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Question 601

[1 marks]Electrolysis and electroplating
Electrolysis is the process in which...
  1. Aa metal is deposited as a coating onto another metal by passing an electric current through an electrolyte containing ions of the coating metal, as in electroplating.
  2. Ban ionic compound is broken down using heat alone, without an electric current, as happens in thermal decomposition.
  3. Can ionic compound is broken down into its elements by passing an electric current through its molten or aqueous solution form.
  4. Da covalent compound's molecules move through a porous membrane under an electric field, with no electrode reactions taking place.

Question 602

[1 marks]Electrolysis and electroplating
During electrolysis, what happens to the cations in the electrolyte?
  1. AThey migrate to the cathode, where they lose electrons and are converted to atoms.
  2. BThey migrate to the anode, where they lose electrons and are converted to atoms.
  3. CThey migrate to the cathode, where they gain electrons and are converted to atoms.
  4. DThey migrate to the anode, where they gain electrons and are converted to atoms.

Question 603

[1 marks]Electrolysis and electroplating
Chromium plating of an iron object is carried out using chromium (III) sulfate, Cr2(SO4)3, as the electrolyte, normally with a chromium anode (Cr(s) → Cr³⁺(aq) + 3e⁻). How would the reaction at the anode be affected if the chromium electrode were replaced by an inert carbon electrode?
  1. AOxygen gas would be produced at the anode, as OH⁻ ions from water are preferentially discharged instead of chromium dissolving.
  2. BChlorine gas would be produced at the anode, as Cl⁻ ions are preferentially discharged.
  3. CHydrogen gas would be produced at the anode, as H⁺ ions are preferentially discharged.
  4. DChromium metal would continue to be deposited at the anode, as with the chromium electrode.

Question 701

[1 marks]Empirical and molecular formulae; reactions of metals with chlorine
In an experiment where dry chlorine gas is passed over a heated metal to form a metal chloride, name a substance that can be used as the drying agent for the chlorine gas.

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Question 702

[1 marks]Empirical and molecular formulae; reactions of metals with chlorine
Iron wool is reacted with dry chlorine gas to form a chloride containing 34,5% iron by mass (so 65,5% chlorine by mass). Using relative atomic masses Fe = 56 and Cl = 35,5, what is the empirical formula of this chloride?
  1. AFe2Cl3
  2. BFeCl2
  3. CFeCl3
  4. DFeCl

Question 703

[1 marks]Empirical and molecular formulae; reactions of metals with chlorine
An iron chloride has empirical formula FeCl3 (empirical formula mass = 56 + 3(35,5) = 162,5) and a relative formula mass of 325. What is its molecular formula?
  1. AFeCl6
  2. BFeCl3
  3. CFe3Cl9
  4. DFe2Cl6

Question 801

[1 marks]Giant covalent structures and polymers
Which of the following correctly describes the structure of diamond?
  1. AEach carbon atom is covalently bonded to three other carbon atoms, forming layers of hexagonal rings that can slide over each other.
  2. BPositive and negative ions are held together in a rigid lattice by strong electrostatic forces, as in an ionic compound such as sodium chloride.
  3. CIndividual molecules are held together by weak forces of attraction between molecules, as in a simple molecular solid such as iodine.
  4. DEach carbon atom is covalently bonded to four other carbon atoms in a rigid three-dimensional structure.

Question 802

[1 marks]Giant covalent structures and polymers
Graphite is a good conductor of electricity while diamond is a poor conductor. This is because...
  1. Agraphite has a lower density than diamond, and materials with lower density conduct electricity better.
  2. Bgraphite has delocalised electrons that move freely along its layers, while diamond has no free or delocalised electrons.
  3. Cdiamond has delocalised electrons that move freely, while all of graphite's electrons are held in fixed covalent bonds.
  4. Dgraphite contains free-moving ions, while diamond contains only covalent bonds.

Question 803

[1 marks]Giant covalent structures and polymers
Name one natural polymer of carbon.

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Question 901

[1 marks]Ethanol: fermentation and dehydration to ethene
State one use of ethanol.

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Question 902

[1 marks]Ethanol: fermentation and dehydration to ethene
Glucose, C6H12O6, is fermented using yeast enzymes to produce ethanol and carbon dioxide. Write a balanced equation for this reaction.

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Question 903

[1 marks]Ethanol: fermentation and dehydration to ethene
A gas is collected from an experiment. Which simple test would confirm that the gas is ethene?
  1. ATest the gas with a lit splint; it burns with a 'pop' sound, as it does when testing for hydrogen gas.
  2. BBubble the gas through limewater; the limewater turns milky, as it does when testing for carbon dioxide gas.
  3. CBubble the gas through bromine water; the orange/brown colour is decolourised.
  4. DTest the gas with a glowing splint; the splint relights, as it does when testing for oxygen gas.

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