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ZIMSEC O Level · 5071/2 · N2017

Chemistry Paper 2 November 2017

Questions
27
Total marks
85
Time allowed
120 min
Syllabus code
5071/2

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Questions
27
Pass mark
17
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Answer every question in the printed order, get marked at the end, then see the answers.

The questions

Question 101

[1 marks]Diffusion of ammonia and hydrogen chloride; methods of purification
Which of the following correctly defines the term diffusion?
  1. AThe movement of particles from a region of higher concentration to a region of lower concentration.
  2. BThe net movement of water molecules from a region of high water potential to a region of low water potential across a partially permeable membrane.
  3. CThe escape of a gas through a small hole into a vacuum.
  4. DThe process by which a solid changes directly into a gas without passing through the liquid state.

Question 102

[1 marks]Diffusion of ammonia and hydrogen chloride; methods of purification
Cotton wool soaked in concentrated ammonia is placed at one end of a glass tube, and cotton wool soaked in concentrated hydrochloric acid is placed at the other end. White fumes of ammonium chloride form off-centre in the tube, closer to the hydrochloric acid end. This happens because...
  1. Aammonia reacts with the glass tube before it can reach the centre, so the fumes form nearer the hydrochloric acid end.
  2. Bhydrogen chloride is denser than air and sinks within the tube, so the fumes form nearer the hydrochloric acid end.
  3. Chydrogen chloride has a smaller molar mass than ammonia, so it diffuses more quickly; the fumes therefore form closer to the hydrochloric acid end.
  4. Dhydrogen chloride has a larger molar mass than ammonia, so it diffuses more slowly; the fumes therefore form closer to the hydrochloric acid end.

Question 103

[1 marks]Diffusion of ammonia and hydrogen chloride; methods of purification
Ammonia gas and hydrogen chloride gas react to produce white fumes of ammonium chloride. Write a balanced chemical equation for this reaction.

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Question 201

[1 marks]Bonding in ammonium nitrate
Ammonium nitrate is made up of an ammonium ion, NH4+, and a nitrate ion, NO3-. Write the chemical formula of ammonium nitrate.

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Question 202

[1 marks]Bonding in ammonium nitrate
In ammonium nitrate, NH4NO3, the bonding between the atoms within the ammonium ion (NH4+) and within the nitrate ion (NO3-) is covalent. The bonding between the ammonium ion and the nitrate ion is...
  1. Ametallic bonding.
  2. Bionic bonding.
  3. Chydrogen bonding.
  4. Dcovalent bonding.

Question 203

[1 marks]Bonding in ammonium nitrate
Which of the following is a physical property of solid ammonium nitrate at room temperature and pressure?
  1. AIt is a good conductor of electricity in the solid state.
  2. BIt is a liquid at room temperature and pressure.
  3. CIt is a strong-smelling gas at room temperature.
  4. DIt is soluble in water.

Question 301

[1 marks]Electrolysis of concentrated sodium chloride; mole and concentration calculations
In the electrolysis of concentrated aqueous sodium chloride using carbon electrodes, what is observed at the cathode?
  1. ABubbles of a colourless gas are given off.
  2. BA brown gas is given off.
  3. CA pale green gas with a sharp smell is given off.
  4. DA black solid is deposited.

Question 302

[1 marks]Electrolysis of concentrated sodium chloride; mole and concentration calculations
A mass of 20.0 g of nitric acid, HNO3 (Mr = 63), was dissolved in 200 cm3 of distilled water. What is the concentration of the resulting solution, in mol/dm3?
  1. A3.17 mol/dm3
  2. B0.32 mol/dm3
  3. C1.59 mol/dm3
  4. D15.9 mol/dm3

Question 303

[1 marks]Electrolysis of concentrated sodium chloride; mole and concentration calculations
In the electrolysis of concentrated aqueous sodium chloride using carbon electrodes, blue litmus paper is held near the anode. What is observed, and why?
  1. AThe litmus paper is bleached white, because chlorine gas is produced at the anode.
  2. BThe litmus paper is unaffected, because no gas reaches it.
  3. CThe litmus paper turns red, because an acidic gas is produced at the anode.
  4. DThe litmus paper turns a darker blue, because an alkaline gas is produced at the anode.

Question 401

[1 marks]Carbon dioxide equilibrium in fizzy drinks; ammonium salts and calcium chloride's role
In the equation CO2(g) <=> CO2(aq), what does the symbol <=> mean?

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Question 402

[1 marks]Carbon dioxide equilibrium in fizzy drinks; ammonium salts and calcium chloride's role
Carbon dioxide dissolves in the water of a fizzy drink to form carbonic acid: CO2(aq) + H2O(l) -> H2CO3(aq). What effect does this have on the pH of the drink?
  1. AIt raises the pH, because carbonic acid is formed.
  2. BIt has no effect on the pH, because carbon dioxide does not react with water.
  3. CIt lowers the pH, because carbon dioxide gas is alkaline.
  4. DIt lowers the pH, because carbonic acid is formed.

Question 403

[1 marks]Carbon dioxide equilibrium in fizzy drinks; ammonium salts and calcium chloride's role
Ammonia (in which nitrogen has an oxidation state of -3) is oxidised by heated copper(II) oxide to form nitrogen gas, copper and water: 3CuO + 2NH3 -> 3Cu + 3H2O + N2. What is the oxidation state of nitrogen in the nitrogen gas, N2, produced?
  1. A-3
  2. B0
  3. C+3
  4. D+5

Question 501

[1 marks]Identifying an organic acid from its structure; preservative use in animal feed
An organic compound A has the structural formula CH3CH2COOH. Name compound A.

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Question 502

[1 marks]Identifying an organic acid from its structure; preservative use in animal feed
Propanoic acid, CH3CH2COOH, reacts with sodium carbonate. What type of reaction is this?
  1. AEsterification.
  2. BOxidation.
  3. CNeutralisation.
  4. DAddition.

Question 503

[1 marks]Identifying an organic acid from its structure; preservative use in animal feed
Propanoic acid is an important ingredient in some animal feeds because...
  1. Ait is a strong oxidising agent that kills bacteria by oxidising them.
  2. Bit is acidic, and the resulting low pH prevents the growth of bacteria that could spoil the feed.
  3. Cit has a sweet taste that improves the palatability of the feed.
  4. Dit is alkaline, and neutralises acidic spoilage products in the feed.

Question 601

[1 marks]Identifying ions in industrial waste water; ammonium ion test; limewater equation
Sodium carbonate was added to a sample of industrial waste water. Bubbles of a gas were given off, and this gas turned limewater milky. Identify the gas produced.

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Question 602

[1 marks]Identifying ions in industrial waste water; ammonium ion test; limewater equation
Aqueous ammonia was added, drop by drop until in excess, to a sample of industrial waste water. A white precipitate formed, and this precipitate then dissolved in the excess aqueous ammonia. Which metal ion is present in the waste water?
  1. AZn2+
  2. BCa2+
  3. CCu2+
  4. DFe3+

Question 603

[1 marks]Identifying ions in industrial waste water; ammonium ion test; limewater equation
Which of the following is a correct chemical test, and expected observation, for the presence of ammonium ions, NH4+, in a solution?
  1. AAdd aqueous barium chloride; a white precipitate forms that is insoluble in excess hydrochloric acid.
  2. BAdd aqueous sodium hydroxide and warm gently; ammonia gas is produced, turning damp red litmus paper blue.
  3. CAdd aqueous sodium hydroxide and warm gently; ammonia gas is produced, turning damp blue litmus paper red.
  4. DAdd dilute hydrochloric acid; a colourless gas is produced that turns limewater milky.

Question 701

[1 marks]Rates of reaction of magnesium and iron with hydrochloric acid
5.0 g samples of powdered magnesium and powdered iron were each reacted separately with equal volumes of 1.0 mol/dm3 hydrochloric acid. Name the gas produced in both reactions.

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Question 702

[1 marks]Rates of reaction of magnesium and iron with hydrochloric acid
5.0 g samples of powdered magnesium and powdered iron were each reacted separately with equal volumes of 1.0 mol/dm3 hydrochloric acid, at the same temperature. Comparing the overall rates at which the two metals produced gas, which statement is correct?
  1. AMagnesium reacts faster than iron because magnesium is more reactive.
  2. BMagnesium and iron react at the same rate because they form the same gas.
  3. CIron reacts faster than magnesium because iron has a larger relative atomic mass.
  4. DIron reacts faster than magnesium because iron is more reactive.

Question 703

[1 marks]Rates of reaction of magnesium and iron with hydrochloric acid
5.0 g samples of powdered magnesium and powdered iron were each reacted separately with equal volumes of 1.0 mol/dm3 hydrochloric acid, at the same temperature. If the experiment were repeated using 5.0 g of powdered zinc under the same conditions, where would the rate of gas production for zinc lie compared with magnesium and iron?
  1. AThe same as magnesium, because zinc and magnesium are in the same group of the periodic table.
  2. BFaster than magnesium, because zinc is the most reactive of the three metals.
  3. CSlower than iron, because zinc is the least reactive of the three metals.
  4. DBetween magnesium and iron, because zinc is more reactive than iron but less reactive than magnesium.

Question 801

[1 marks]Alloys; titration of an iron alloy with potassium dichromate
Brass is an alloy of two metals. Name the two metals that make up brass.

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Question 802

[1 marks]Alloys; titration of an iron alloy with potassium dichromate
A 1.00 g sample of an iron alloy was dissolved in dilute sulphuric acid. The resulting solution was titrated with 0.1 mol/dm3 aqueous potassium dichromate, K2Cr2O7. A volume of 18.00 cm3 of the potassium dichromate solution was needed to reach the end point. How many moles of potassium dichromate were used?
  1. A0.00018 mol
  2. B0.018 mol
  3. C0.0018 mol
  4. D1.8 mol

Question 803

[1 marks]Alloys; titration of an iron alloy with potassium dichromate
A 1.00 g sample of an iron alloy was dissolved in dilute sulphuric acid and titrated with 0.1 mol/dm3 aqueous potassium dichromate, K2Cr2O7, requiring 18.00 cm3 to reach the end point. The titration reaction is 6Fe2+(aq) + Cr2O7^2-(aq) + 14H+(aq) -> 6Fe3+(aq) + 2Cr3+(aq) + 7H2O(l). Given that A(Fe) = 56, what mass of iron was present in the 1.00 g alloy sample?
  1. A0.605 g
  2. B0.101 g
  3. C0.702 g
  4. D1.21 g

Question 901

[1 marks]Isomers of pentane; reactions of ethene
Which of the following correctly defines the term isomers?
  1. ACompounds with different molecular formulae and different structural formulae but the same relative molecular mass.
  2. BCompounds with the same structural formula but different molecular formulae.
  3. CCompounds with the same molecular formula but different structural formulae.
  4. DCompounds with the same molecular formula and the same structural formula but different physical states.

Question 902

[1 marks]Isomers of pentane; reactions of ethene
How many structural isomers does the alkane with molecular formula C5H12 have?

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Question 903

[1 marks]Isomers of pentane; reactions of ethene
Ethene reacts with a reagent z to form 1,2-dibromoethane, CH2BrCH2Br. What is reagent z?
  1. AHydrogen, in the presence of a nickel catalyst.
  2. BBromine water (or liquid bromine).
  3. CAcidified potassium manganate(VII).
  4. DSteam, in the presence of a catalyst.

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