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Paper 2 · Electrolysis and electroplating

Molten lead(II) bromide is electrolysed using inert graphite electrodes. Which equation represents the reaction that occurs at the cathode?

A2Br- -> Br2 + 2e-
BPb -> Pb2+ + 2e-
CPb2+ + 2e- -> Pb
D2H2O -> O2 + 4H+ + 4e-
Explanation: In molten lead(II) bromide, Pb2+ ions are reduced at the cathode: Pb2+ + 2e- -> Pb.

Derived from ZIMSEC Chemistry 5071/2 Paper 2 Theory, November 2013, Q4

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