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Paper 2 · November 2002 · Thermochemistry and Energetics

In the Born-Haber cycle for aluminium oxide shown, the enthalpy change ΔH6=−15300.1 kJ mol−1\Delta H_6 = -15300.1\ kJ\,mol^{-1} is

Athe lattice enthalpy of Al2O3Al_2O_3
Bthe first electron affinity of oxygen
Cthe enthalpy change of atomisation of aluminium
Dthe enthalpy change of formation of Al2O3Al_2O_3

Explanation

It is the strongly exothermic step in which gaseous Al3+Al^{3+} and O2−O^{2-} ions come together to form the solid lattice.

Derived from ZIMSEC Chemistry Paper 2, November 2002, Q1

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