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Paper 2 · periodicity and ionisation energy

Fig. 1 shows the first ionisation energies of the elements sodium to argon. The value for aluminium is lower than that for magnesium because the electron removed from aluminium

periodicity and ionisation energy - ZIMSEC Chemistry past paper diagram
Acomes from a 3p orbital, which is higher in energy than the 3s
Bcomes from a completely filled 3s orbital
Cexperiences a greater nuclear charge
Dis closer to the nucleus
Explanation: The 3p electron of aluminium is slightly further from the nucleus and better shielded, so it is easier to remove.

Derived from ZIMSEC Chemistry Paper 2, June 2014, Q1

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