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ZIMSEC O Level · 4024/1 · N2019

Chemistry Paper 1 November 2019

Questions
39
Time allowed
60 min
Syllabus code
4024/1

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Questions
39
Pass mark
24
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Answer every question in the printed order, get marked at the end, then see the answers.

The questions

Question 1

Diffusion
Which gas has the smallest rate of diffusion?
  1. Amethane
  2. Bammonia
  3. Ccarbon dioxide
  4. Dhydrogen chloride

Question 2

Ions
Which diagram correctly represents a sulphide ion, S2−^{2-}?
  1. AA
  2. BB
  3. CC
  4. DD

Question 3

Experimental techniques
Which apparatus is used to measure an exact volume of 25.00 cm3^3?
  1. Aa 50.00 cm3^3 burette
  2. Ba 25.00 cm3^3 pipette
  3. Ca 25.00 cm3^3 conical flask
  4. Da 25.00 cm3^3 measuring cylinder

Question 4

What is the volume occupied by three moles of carbon dioxide at r.t.p?
  1. A24 dm3^3
  2. B28 dm3^3
  3. C72 dm3^3
  4. D84 dm3^3

Question 5

Chemical formulae
The chemical formula 2NH3_3 represents
  1. Asix molecules of hydrogen.
  2. Btwo molecules of ammonia.
  3. Ctwo molecules of nitrogen.
  4. Dtwo atoms of ammonia.

Question 6

Energy changes
An exothermic reaction is one which has
  1. Amore gaseous reactants than products.
  2. Bmore gaseous products than reactants.
  3. Ca greater bond formation energy than bond breaking energy.
  4. Da greater bond breaking energy than bond formation energy.

Question 7

Extraction of metals
The main function of limestone in the blast furnace is to
  1. Aoxidise iron ore.
  2. Breduce iron ore.
  3. Cremove impurities.
  4. Dremove excess carbon.

Question 8

Water pollution
Which gas decreases in concentration during eutrophication in a pond?
  1. Ahydrogen
  2. Bmethane
  3. Cnitrogen
  4. Doxygen

Question 9

Waste management
Which method of waste disposal is a source of carcinogens?
  1. Abio-digestion
  2. Bincineration
  3. Crecycling
  4. Dlandfilling

Question 10

Redox
What happens to the oxidation number of nickel when nickel ore, NiS, is changed to pure nickel?
  1. Aincreases to +1
  2. Bdecreases to zero
  3. Cdecreases to +2
  4. Dincreases to zero

Question 11

Pollution
Which chemical is a pollutant from gold processing?
  1. AHg
  2. BAl2_2(SO4_4)3_3
  3. CHCl
  4. DPb

Question 12

Industrial chemistry

The stages show reactions that occur in the contact process.

At which stage is the formation of an acid spray prevented?

  1. AS + O2_2 →\rightarrow SO2_2
  2. B2SO2_2 + O2_2 ⇌\rightleftharpoons 2SO3_3
  3. CSO3_3 + H2_2SO4_4 →\rightarrow H2_2S2_2O7_7
  4. DH2_2S2_2O7_7 + H2_2O →\rightarrow 2H2_2SO4_4

Question 13

Metals
Which one is a chemical property of a metal?
  1. Aforms positive ions
  2. Bforms negative ions
  3. Cforms acidic oxides
  4. Dforms coloured solutions

Question 14

Reactivity series
Which element is least reactive?
  1. AFe
  2. BMg
  3. CNa
  4. DZn

Question 16

Alloys
Which metal is added to steel to give it anti-corrosion properties?
  1. Achromium
  2. Bcopper
  3. Czinc
  4. Dgold

Question 17

Acids and bases

The pH values of four solutions, W, X, Y and Z, are shown in the table.

Solution W has pH 3, X has pH 5, Y has pH 7 and Z has pH 11.

Which solution can be used to neutralize an acidic soil?

  1. AW
  2. BX
  3. CY
  4. DZ

Question 18

Salt preparation
The correct order of preparing some salts from a metal and an acid is
  1. Acrystallisation →\rightarrow evaporation →\rightarrow displacement →\rightarrow filtration.
  2. Bdisplacement →\rightarrow filtration →\rightarrow evaporation →\rightarrow crystallisation.
  3. Cevaporation →\rightarrow crystallisation →\rightarrow filtration →\rightarrow displacement.
  4. Dfiltration →\rightarrow evaporation →\rightarrow displacement →\rightarrow crystallisation.

Question 19

Redox

Which substance is reduced in the reaction shown?

CaO + C →\rightarrow Ca + CO2_2

  1. ACaO
  2. BC
  3. CCa
  4. DCO2_2

Question 20

Which is not a reason for electroplating metals?
  1. Adecorating
  2. Bprotecting
  3. Cimproving purity
  4. Dimproving electrical conductivity

Question 21

Water
Lathering of soap is a test for the
  1. Apurity of water.
  2. Bacidity of water.
  3. Chardness of water.
  4. Dalkalinity of water.

Question 22

Stoichiometry

Ammonia gas reacts with dilute hydrochloric acid as shown in the equation:

NH3(g)_{3(g)} + HCl(aq)_{(aq)} →\rightarrow NH4_4Cl(aq)_{(aq)}

What mass of ammonium chloride is formed if 8.5 g of ammonia gas is used?

  1. A2.70 g
  2. B4.25 g
  3. C8.50 g
  4. D26.75 g

Question 23

Empirical formula

An organic compound has 92.3 % carbon and 7.7 % hydrogen by mass.

The empirical formula of the compound is

  1. AC3_3H5_5.
  2. BC2_2H3_3.
  3. CCH2_2.
  4. DCH.

Question 24

Empirical formula

A hydrocarbon has an empirical formula of CH2_2 and a relative molecular mass of 28.

What is the percentage composition of carbon in the hydrocarbon?

  1. A14 %
  2. B21 %
  3. C50 %
  4. D86 %

Question 25

Redox

A breathalizer is an instrument used to measure the amount of alcohol in a breath. The device contains potassium dichromate which reacts with alcohol in the breath.

If the breath contains alcohol the colour changes from

  1. Agreen to orange.
  2. Borange to green.
  3. Cpink to purple.
  4. Dpurple to pink.

Question 26

Hydrocarbons
Which molecular formula could be that of candle wax?
  1. AC4_4H10_{10}
  2. BC6_6H12_{12}
  3. CC8_8H18_{18}
  4. DC20_{20}H42_{42}

Question 27

Esters

Ethanoic acid reacts with methanol according to the equation

CH3_3COOH + CH3_3OH →\rightarrow CH3_3COOCH3_3 + H2_2O

What is the name of the ester formed?

  1. Amethylpropanoate
  2. Bmethylethanoate
  3. Cethylethanoate
  4. Dethylmethanoate

Question 28

Cracking

A hydrocarbon, X, can crack as shown

X →heat\xrightarrow{\text{heat}} C2_2H4_4 + C8_8H18_{18}

What could be X?

  1. AC6_6H14_{14}
  2. BC8_8H18_{18}
  3. CC10_{10}H22_{22}
  4. DC16_{16}H36_{36}

Question 29

Combustion
One of the products of heating methane in excess oxygen is
  1. Acarbon.
  2. Bsoot.
  3. Ccarbon monoxide.
  4. Dcarbon dioxide.

Question 30

Polymers

Amino acids react to form a large protein molecule and water as shown.

amino acids →\rightarrow protein molecule + water.

The process is called

  1. Ahydrolysis.
  2. Belimination.
  3. Caddition polymerisation.
  4. Dcondensation polymerisation.

Question 31

Organic chemistry

An organic compound Q reacted with one mole of hydrogen in the presence of a catalyst.

What could be Q?

  1. Aan alcohol
  2. Ba carboxylic acid
  3. Can alkene
  4. Dan alkane

Question 32

Which reaction can be used to distinguish ethane from ethene?
  1. Areacting both with chlorine in UV light
  2. Breacting both with bromine water in UV light
  3. Creacting both with bromine water in the dark
  4. Dreacting both with hydrogen gas

Question 33

Organic reactions
The reaction between an alkene and bromine in the dark is
  1. Aan addition reaction.
  2. Ban oxidation reaction.
  3. Ca reduction reaction.
  4. Da polymerisation reaction.

Question 34

Energy changes

The diagrams show some energy profiles of different reactions.

Which diagram represents the reaction with the largest negative enthalpy change of reaction?

  1. AA
  2. BB
  3. CC
  4. DD

Question 35

Qualitative analysis

A solution of silver nitrate was placed in four different test tubes and subjected to different tests as shown in the diagram.

In which test tube will the red litmus paper change to blue?

  1. AA
  2. BB
  3. CC
  4. DD

Question 36

Polymers
Packaging material made of polyethene cannot be disposed of by land filling because it is
  1. Apoisonous to animals.
  2. Bnon biodegradable.
  3. Ca condensation polymer.
  4. Dan addition polymer.

Question 37

Medicines
Which statement is true about the use of plants in traditional medicine?
  1. Athere are clear prescriptions and dosages
  2. Bthey can improve the health of a person
  3. Cthey are not poisonous
  4. Dthey do not cause any allergies

Question 38

Separation techniques
Purity of a substance can be tested by
  1. Acrystallisation.
  2. Bchromatography.
  3. Cfiltration.
  4. Dprecipitation.

Question 39

Water treatment
In the purification of water the coagulant used is
  1. Aaluminium sulphate.
  2. Bpotassium sulphate.
  3. Ccopper sulphate.
  4. Dbarium sulphate.

Question 40

Minerals
Which statement correctly defines the term *mineral beneficiation*?
  1. Aexporting the ore for quick cash benefits
  2. Busing the ore to benefit the community
  3. Cprocessing ore to add value and fetch higher prices
  4. Dselling precious stones on the black market to benefit from the high prices

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