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ZIMSEC O Level · 4024/1 · N2018

Chemistry Paper 1 November 2018

Questions
40
Time allowed
60 min
Syllabus code
4024/1

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Questions
40
Pass mark
24
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Answer every question in the printed order, get marked at the end, then see the answers.

The questions

Question 1

Chromatography

An investigation to identify the ink used to make a fake one hundred dollar note using paper chromatography was carried out. The chromatogram shown was obtained.

The dye(s) present in the fake note are/were

  1. A3, 4 and 5
  2. B2 and 3
  3. C6 only
  4. D3 and 4

Question 2

Atomic structure
Which pair correctly describes the structure of an atom?
  1. Aorbiting the nucleus: protons; in the nucleus: electrons and neutrons
  2. Borbiting the nucleus: electrons and neutrons; in the nucleus: protons
  3. Corbiting the nucleus: electrons; in the nucleus: protons and neutrons
  4. Dorbiting the nucleus: protons and neutrons; in the nucleus: electrons

Question 3

Atomic structure
What is the electronic configuration of the silicon isotope, 1430^{30}_{14}Si?
  1. A2. 8. 4
  2. B4. 8. 2
  3. C2. 8. 8. 8. 4
  4. D8. 4. 2

Question 4

Ionic bonding
Which row correctly gives the physical properties of an ionic compound?
  1. Amelting point high; conductivity when solid none; conductivity when molten none
  2. Bmelting point low; conductivity when solid conducts; conductivity when molten conducts
  3. Cmelting point high; conductivity when solid none; conductivity when molten conducts
  4. Dmelting point low; conductivity when solid none; conductivity when molten none

Question 5

Chemical bonding

The table shows the atomic numbers of two elements, P and Q.

Element P has atomic number 19; element Q has atomic number 17.

Elements P and Q can combine to form

  1. Aa covalent compound PQ.
  2. Ba covalent compound PQ2_2.
  3. Can ionic compound PQ.
  4. Dan ionic compound PQ2_2.

Question 6

Ionic bonding
What is the correct formula of the compound formed between M+^+ and Z2−^{2-}?
  1. AMZ
  2. BMZ2_2
  3. CM2_2Z
  4. DM2_2Z2_2

Question 7

Covalent bonding
Which structure correctly shows the bonding in carbon dioxide?
  1. AA
  2. BB
  3. CC
  4. DD

Question 8

Solutions and concentration
A 0.1 mol dm−3^{-3} solution of sodium carbonate can be prepared by dissolving
  1. A106 g of Na2_2CO3(s)_{3(s)} in 100 cm3^3 of water
  2. B10.6 g of Na2_2CO3(s)_{3(s)} in 100 cm3^3 of water
  3. C10.6 g of Na2_2CO3(s)_{3(s)} in 1000 cm3^3 of water
  4. D106 g of Na2_2CO3(s)_{3(s)} in 1000 cm3^3 of water

Question 9

Ionic equations

Phosphoric acid and potassium hydroxide react according to the equation:

H3_3PO4(aq)_{4(aq)} + 3KOH(aq)_{(aq)} →\rightarrow K3_3PO4(aq)_{4(aq)} + 3H2_2O(l)_{(l)}

Which ions will not appear in the ionic equation?

  1. AH(aq)+^+_{(aq)} and OH(aq)−^-_{(aq)}
  2. BK(aq)+^+_{(aq)} and PO43−(aq)_4^{3-}{}_{(aq)}
  3. CH(aq)−^-_{(aq)} and PO43−(aq)_4^{3-}{}_{(aq)}
  4. DK(aq)+^+_{(aq)} and OH(aq)−^-_{(aq)}

Question 10

Which equation does not result in a change of oxidation state of the species involved?
  1. AFe(aq)2+^{2+}_{(aq)} →\rightarrow Fe(aq)3+^{3+}_{(aq)} + e−^-
  2. BCu(aq)2+^{2+}_{(aq)} + CO32−(aq)_3^{2-}{}_{(aq)} →\rightarrow CuCO3(s)_{3(s)}
  3. C2H2(g)_{2(g)} + O2(g)_{2(g)} →\rightarrow 2H2_2O(l)_{(l)}
  4. DAg(aq)+^+_{(aq)} + e−^- →\rightarrow Ag(s)_{(s)}

Question 11

Energy changes
The production of carbohydrates during photosynthesis is an example
  1. Aan endothermic reaction.
  2. Ba combustion reaction.
  3. Can exothermic reaction.
  4. Da displacement reaction.

Question 12

Sulphur dioxide reacts with oxygen according to the equation:

2SO2(g)_{2(g)} + O2(g)_{2(g)} ⇌\rightleftharpoons 2SO3(g)_{3(g)} Δ\DeltaH = -188 kJ/mol

Which factor increases the amount of sulphur trioxide produced?

  1. Aincrease in temperature
  2. Bdecrease in temperature
  3. Cincrease in amount of catalyst
  4. Ddecrease in pressure

Question 13

Reactivity series

A new element has been discovered and is believed to be between zinc and lead in the electrochemical series.

How will the element react with solutions of zinc sulphate and lead nitrate?

  1. Azinc displaced; lead remains in solution
  2. Bzinc remains in solution; lead displaced
  3. Czinc displaced; lead displaced
  4. Dzinc remains in solution; lead remains in solution

Question 14

Carbonates
When heated, a metal carbonate decomposes to form
  1. Ametal oxide and carbon
  2. Bcarbon dioxide and metal
  3. Ccarbon monoxide and metal oxide
  4. Dcarbon dioxide and metal oxide

Question 15

Air
Nitrogen and oxygen are separated from liquid air by the process of
  1. Aliquefaction
  2. Bsolidification
  3. Cfractional distillation
  4. Dcondensation

Question 16

Qualitative analysis
Which reagent could be used to distinguish between aluminium nitrate and zinc nitrate?
  1. Asodium hydroxide solution
  2. Bammonia solution
  3. Cbarium chloride solution
  4. Dsilver nitrate solution

Question 17

Empirical formula

A compound of nitrogen and hydrogen contains 87.5 % nitrogen.

What is its empirical formula?

  1. AN2_2
  2. BNH2_2
  3. CN2_2H2_2
  4. DN2_2H4_4

Question 18

Air
Respiration, combustion and rusting are chemical processes which all use
  1. Awater.
  2. Bheat energy.
  3. Ccarbon dioxide.
  4. Doxygen.

Question 19

Transition metals
Which one is not a property of transition metal ions?
  1. AThey act as catalysts.
  2. BTheir solutions are colourless.
  3. CTheir solutions are coloured.
  4. DThey have many oxidation states.

Question 20

Extraction of metals
Which pair correctly matches a metal and its extraction method?
  1. Airon -- electrolysis
  2. Bplatinum -- reduction
  3. Cgold -- electrolysis
  4. Dnickel -- reduction

Question 21

Extraction of metals
In the blast furnace, molten iron is tapped off at the bottom of the furnace while slag settles above the molten iron because
  1. Aslag is more dense than molten iron.
  2. Bslag is less dense than molten iron.
  3. Cmolten iron and slag have the same density.
  4. Dmolten iron occupies more space than slag.

Question 22

Metals
Copper metal is used in electrical wiring and manufacture of pots and pans because of its
  1. Ahigh conductivity
  2. Bhigh reactivity
  3. Ccheap cost of production
  4. Dabundance in nature

Question 23

Which structures represents the same compound?
  1. A2 and 4
  2. B1 and 2
  3. C1 and 3
  4. D2 and 3

Question 24

Organic chemistry
Which homologous series of organic compounds has the general formula Cn_nH2n_{2n}?
  1. Aalcohols
  2. Bcarboxylic acids
  3. Calkanes
  4. Dalkenes

Question 25

Organic reactions
When two molecules react to form one molecule, this is
  1. Aan addition reaction.
  2. Ba substitution reaction.
  3. Ca condensation reaction.
  4. Dan esterification reaction.

Question 26

Organic chemistry

Ethene may be manufactured according to the reaction:

C2_2H6_6 →heat\xrightarrow{\text{heat}} C2_2H4_4 + H2_2

What type of reaction is this?

  1. Apolymerisation
  2. Bcracking
  3. Caddition
  4. Dhydrogenation

Question 27

Organic chemistry
Which one is an example of a saturated hydrocarbon?
  1. Abutane
  2. Bethanol
  3. Cbutene
  4. Dbutanol

Question 28

Esters
Which compounds react to form ethylethanoate?
  1. Aethane and ethanol
  2. Bethanoic acid and ethanol
  3. Cethene and ethanoic acid
  4. Dethane and ethanoic acid

Question 29

Polymers
Which structural formula represents nylon?
  1. AA
  2. BB
  3. CC
  4. DD

Question 30

Polymers
Which monomer unit polymerises to form starch?
  1. AA
  2. BB
  3. CC
  4. DD

Question 31

Water treatment
Which process describes the secondary stage of sewage treatment?
  1. Asedimentation
  2. Bsludge activation
  3. Cprecipitation
  4. Ddischarge

Question 32

Water pollution
Which ion is common to both sewage and fertilizers?
  1. Anitrate
  2. Bcarbonate
  3. Cchloride
  4. Dsulphate

Question 33

Air pollution
Which process increases the amount of sulphur dioxide in the air?
  1. Aburning methane
  2. Bburning coal
  3. Cburning wood
  4. Dburning ethene

Question 34

Air pollution
Which pair correctly matches a pollutant gas and its effect on the environment?
  1. ASO2_2 -- depletes the ozone layer
  2. BNO2_2 -- global warming
  3. CCFC -- form photochemical smog
  4. DCO2_2 -- global warming

Question 35

Air pollution
Oxides of nitrogen are produced in car engines because the
  1. Abonds in nitrogen gas are easy to break.
  2. Breactions can take place without interference.
  3. Ccar engines have high temperatures for this reaction.
  4. Dreaction only need moderate warmth to proceed.

Question 36

Waste management
All of the following are used in waste management except
  1. Acomposting.
  2. Bsource reduction.
  3. Cincineration.
  4. Dlogging.

Question 37

Charcoal is used in the purification of water because it
  1. Acoagulates the water.
  2. Bremoves inorganic ions.
  3. Cmakes water colourless.
  4. Ddisinfects the water.

Question 38

Energy changes

The diagram shows the energy profile for the reaction

N2(g)_{2(g)} + O2(g)_{2(g)} →\rightarrow 2NO(g)_{(g)}.

What is the energy change X?

  1. Aenthalpy of combustion
  2. Bbond energy
  3. Centhalpy of reaction
  4. Dactivation energy

Question 39

Medicines
Which one is an advantage of using herbal medicines?
  1. Aherbal medicines cure better than pharmaceutical medicines.
  2. Bherbal medicines are easily metabolized because they are organic.
  3. Cherbal medicines are cheaper than pharmaceutical medicines.
  4. Dherbal medicines have clear directions for use.

Question 40

Fuels
Which chemical process takes place during the production of biodiesel?
  1. Aesterification
  2. Baddition
  3. Chydrogenation
  4. Dcombustion

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