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Paper 3 · November 2009 · Electrochemistry

An acidic solution of MnO_4^{2-}_{(aq)} undergoes the reaction shown below:

3MnO_4^{2-}_{(aq)} + 4H^+_{(aq)} \rightarrow 2MnO_4^-_{(aq)} + MnO_{2(s)} + 2H_2O_{(l)}

Which statement about the reaction is correct?

AMnO42−MnO_4^{2-} is reduced to MnO4−MnO_4^-
BMnO4−MnO_4^- is reduced to MnO42−MnO_4^{2-}
CMnO42−MnO_4^{2-} is oxidised to MnO4−MnO_4^-
DMnO42−MnO_4^{2-} is oxidised to MnO2MnO_2

Explanation

The marking scheme gives answer C. In MnO42−MnO_4^{2-}, Mn is +6. In MnO4−MnO_4^-, Mn is +7 (oxidised). In MnO2MnO_2, Mn is +4 (reduced). So MnO42−MnO_4^{2-} is both oxidised (to MnO4−MnO_4^-) and reduced (to MnO2MnO_2) — this is disproportionation. The statement that MnO42−MnO_4^{2-} is oxidised to MnO4−MnO_4^- is correct.

ZIMSEC Chemistry Paper 3, November 2009, Q2

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